1887

Abstract

Summary

This paper discusses the effect of microwaves on the flocculation of asphaltene particles. A sample of Dehlor heavy oil from southwestern Iran was exposed to microwave radiation under anoxic conditions and saturated with helium gas at intervals of 3, 6, and 9 minutes. Then, using a viscometer and normal heptane, the set point of asphaltene flocculation was determined for each sample. The results of the experiments showed that three minutes of exposure to microwave irradiation caused the asphaltene to be flocculated from 34 vol% normal heptanes in the crude sample to 41 vol%. In other words, microwaves inhibited asphaltene aggregation. Based on the results of SARA (Saturation, Aromatics, Resin, Asphaltene) analysis, the largest reduction in asphaltene composition in heavy oil occurred at the 3 min interval. In contrast, at 6 and 9 min, the greatest decrease was observed for resin compounds, which are themselves a natural inhibitor of flocculation. Changes in the structure and reduction of sulfur and nitrogen components of asphaltene also cause microwaves to act as an inhibitor in the flocculation of asphaltene particles. Therefore, reducing the amount of asphaltene compounds and eliminating polar compounds, which is a function of time interval for microwave radiation, delays asphaltene aggregation.

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/content/papers/10.3997/2214-4609.201800144
2018-04-09
2024-04-24
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References

  1. Al-Sahhaf, T. A. Fahim, M. A. Elkilani, A. S.
    [2002] Retardation of asphaltene precipitation by addition of toluene, resins, deasphalted oil and surfactants. Fluid phase equilibria, 194, 1045–1057.
    [Google Scholar]
  2. Bezerril, R.H. ZanbottoRamalho A.M.Souza K.R.da Silva D.R.da Mata W.Barillas J.L.M.
    [2009] New Method for Extraction Oils and Greases from Produced Water Using Microwave Techniques. SPE 123005.
    [Google Scholar]
  3. Branco, V. A. M.Mansoori, G. A.Xavier, L. C. D. A.Park, S. J.Manafi, H.
    [2001] Asphaltene flocculation and collapse from petroleum fluids. Journal of Petroleum Science and Engineering, 32(2), 217–230.
    [Google Scholar]
  4. Daaou, M. Larbi, A. Martínez-Haya, B. Rogalski, M.
    [2016] A Comparative study of the chemical structure of asphaltenes from Algerian petroleum collected at different stages of extraction and processing. Journal of Petroleum Science and Engineering, 138, 50–56.
    [Google Scholar]
  5. Escobedo, J. Mansoori, G. A.
    [1995] Viscometric determination of the onset of asphaltene flocculation: A novel method. SPE production & facilities, 10(02), 115–118.
    [Google Scholar]
  6. González, G. Middea, A.
    [1991] Peptization of asphaltene by various oil soluble amphiphiles. Colloids and Surfaces, 52, 207–217.
    [Google Scholar]
  7. LeadbeaterN. E.
    Microwave Heating as a Tool for Sustainable Chemistry. Taylor & Francis Group. 2010.
    [Google Scholar]
  8. Mousavi-Dehghani, S. A. Riazi, M. R. Vafaie-Sefti, M. Mansoori, G. A.
    [2004] An analysis of methods for determination of onsets of asphaltene phase separations. Journal of Petroleum Science and Engineering, 42(2), 145–156.
    [Google Scholar]
  9. Shadman, M. M.Dehghanizadeh, M. SaeediDehaghani, A. H. VafaieSefti, M.Mokhtarian, N.
    [2014] An investigation of the effect of aromatic, anionic and nonionic inhibitors on the onset of asphaltene precipitation. Journal of Oil, Gas and Petrochemical Technology, 1, 17–28.
    [Google Scholar]
  10. Taheri-Shakib, J. Shekarifard, A. Naderi, H. HosseiniS. A.
    [2017] Effect of Microwave Irradiation on Wax and Asphaltene Content of Heavy Crude Oil, In 79th EAGE Conference and Exhibition 2017.
    [Google Scholar]
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