1887

Abstract

Summary

Equation of state (EOS), void volume, pressure sensor accuracy and blank test are identified as major factors to affect the accurate measurement of gas adsorption capacity on shale. In the EOS, the Se-W equation is the most suitable for the calculation of the methane adsorption capacity of the shale, and the second is the S-R-K equation. P-R equation is the worst. Adsorption capacity of shale is negatively related with void volume. The void volume has an error that measurement value is larger than real, which would result in reducing adsorption capacity of the shale in test. Under the condition of high pressure, the effect of void volume error on the adsorption quantity is more serious. Comparison with the temperature sensor, the influence of pressure sensor accuracy on the shale methane adsorption capacity is more prominent. The adsorption capacity test accuracy and stability of measurement system with 10–4 precision pressure sensor superior to that with 10–3 precision pressure sensor. In addition, the test adsorption capacity of the shale which is not corrected by the blank test is usually lower than the actual adsorption capacity, and possibly leads to negative values of adsorption.

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/content/papers/10.3997/2214-4609.201801307
2018-06-11
2024-04-19
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References

  1. EIA
    EIA. 2011. World shale gas resource: an initial assessment of 14 regions outside the United States[R]:4–56.
    [Google Scholar]
  2. JiaChengzao, MinZheng and ZhangYongfeng
    . 2012. Unconventional hydrocarbon resources in China and the prospect of exploration and development[J]. Petroleum Exploration and Development, 39(2):129–136.
    [Google Scholar]
  3. DongDazhong, ZouCaineng, and YangHua
    . 2012. Progress and prospects of shale gas exploration and development in China[J]. Acta Petrolei Sinica, 33(supplement): 107–114.
    [Google Scholar]
  4. Gasparik, M., Ghanizadeh, A., Gensterblum, Y., and Krooss, B. M.
    2013. “Multi-temperature” method for high-pressure sorption measurements on moist shales. Review of Scientific Instruments, 84(8), 085116.
    [Google Scholar]
  5. Ross, D. J., and Bustin, R. M.
    2007. Impact of mass balance calculations on adsorption capacities in microporous shale gas reservoirs[J]. Fuel, 86(17–18):2696–2706.
    [Google Scholar]
  6. 2006. Sediment geochemistry of the lower Jurassic Gordondale member, northeastern British Columbia. Bulletin of Canadian Petroleum Geology, 54(4), 337–365.
    [Google Scholar]
  7. Gasparik, M., Rexer, T.F.T., Aplin, A.C., Billemont, P., De Weireld, G., Gensterblum, Y., Henry, M., Krooss, B.M., Liu, S., Ma, X., Sakurovs, R., Song, Z., Staib, G., Thomas, K.M., Wang, S. and Zhang, T.
    2014. First international inter-laboratory comparison of high-pressure CH4, CO2 and C2H6 sorption isotherms on carbonaceous shales, International Journal Of Coal Geology. 132:131–146.
    [Google Scholar]
  8. RedlichO, KwongJ.
    1949. On the thermodynamics of solutions. V: an equation of state fugacities of gaseous solutions[J]. Chemical Reviews, 44(1): 233–244.
    [Google Scholar]
  9. SoaveG.
    1972. Equilibrium constants from a modified Redlich-Kwong equation of state[J]. Chemical Engineering Science, 27(6): 1197–1203.
    [Google Scholar]
  10. RobinsonD B, PengD, ChungS Y
    . 1985. The development of the Peng-Robinson equation and its application to phase equilibrium in a system containing methanol[J]. Fluid Phase Equilibria, 24(1): 25–41.
    [Google Scholar]
  11. M. Benedict, G.B.
    1940. Webb, L.C.Rubin. J. Chem. Phys., (8), 334–345
    [Google Scholar]
  12. SetzmannU, WagnerW.
    1991. A New Equation of State and Tables of Thermodynamic Properties for Methane Covering the Range from the Melting Line to 625 K at Pressures up to 100 MPa[J]. Journal of Physical & Chemical Reference Data, 20(6):1061–1155.
    [Google Scholar]
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