Resolving the Pore Structure and Sorption Properties of Methane in Mudrocks - A Small Angle Neutron Scattering Study

References

1. Bahadur, J., Ruppert, L.F., Pipich, V., Sakurovs, R. and Melnichenko, Y.B.
   , 2018. Porosity of the Marcellus Shale: A contrast matching small-angle neutron scattering study. International Journal of Coal Geology, 188, pp.156–164.
   [Google Scholar]
2. Busch, A. and Gensterblum, Y.
   , 2011. CBM and CO2-ECBM related sorption processes in coal: a review. International Journal of Coal Geology, 87(2), pp.49–71.
   [Google Scholar]
3. Chathoth, S.M., Mamontov, E., Melnichenko, Y.B. and Zamponi, M.
   , 2010. Diffusion and adsorption of methane confined in nanoporous carbon aerogel: A combined quasi-elastic and small-angle neutron scattering study. Microporous and Mesoporous Materials, 132(1–2), pp.148–153.
   [Google Scholar]
4. Eberle, A.P., King, H.E., Ravikovitch, P.I., Walters, C.C., Rother, G. and Wesolowski, D.J.
   , 2016. Direct measure of the dense methane phase in gas shale organic porosity by neutron scattering. Energy & Fuels, 30(11), pp.9022–9027.
   [Google Scholar]
5. Gasparik, M., Ghanizadeh, A., Bertier, P., Gensterblum, Y., Bouw, S. and Krooss, B.M.
   , 2012. High-pressure methane sorption isotherms of black shales from the Netherlands. Energy & fuels, 26(8), pp.4995–5004.
   [Google Scholar]
6. Gasparik, M., Ghanizadeh, A., Gensterblum, Y. and Krooss, B.M.
   , 2013. “Multi-temperature” method for high-pressure sorption measurements on moist shales. Review of Scientific Instruments, 84(8), p. 085116.
   [Google Scholar]
7. Gasparik, M., Bertier, P., Gensterblum, Y., Ghanizadeh, A., Krooss, B.M. and Littke, R.
   , 2014. Geological controls on the methane storage capacity in organic-rich shales. International Journal of Coal Geology, 123, pp.34–51.
   [Google Scholar]
8. Gasparik, M., Gensterblum, Y., Ghanizadeh, A., Weniger, P. and Krooss, B.M.
   , 2015. High-pressure/high-temperature methane-sorption measurements on carbonaceous shales by the manometric method: experimental and data-evaluation considerations for improved accuracy. SPE Journal, 20(04), pp.790–809.
   [Google Scholar]
9. Gensterblum, Y., Van Hemert, P., Billemont, P., Busch, A., Charriere, D., Li, D., Krooss, B.M., De Weireld, G., Prinz, D. and Wolf, K.H.
   , 2009. European inter-laboratory comparison of high pressure CO2 sorption isotherms. I: Activated carbon. Carbon, 47(13), pp.2958–2969.
   [Google Scholar]
10. Gensterblum, Y., Van Hemert, P., Billemont, P., Battistutta, E., Busch, A., Krooss, B.M., De Weireld, G. and Wolf, K.H.
    , 2010. European inter-laboratory comparison of high pressure CO2 sorption isotherms II: Natural coals. International Journal of Coal Geology, 84(2), pp.115–124.
    [Google Scholar]
11. Hjelm, R.P., Wampler, W.A., Seeger, P.A. and Gerspacher, M.
    , 1994. The microstructure and morphology of carbon black: A study using small angle neutron scattering and contrast variation. Journal of materials research, 9(12), pp.3210–3222.
    [Google Scholar]
12. Marr, D.W.M., Wartenberg, M., Schwartz, K.B., Agamalian, M.M. and Wignall, G.D.
    , 1997. Void morphology in polyethylene/carbon black composites. Macromolecules, 30(7), pp.2120–2124.
    [Google Scholar]
13. Mastalerz, M., He, L., Melnichenko, Y.B. and Rupp, J.A.
    , 2012. Porosity of coal and shale: Insights from gas adsorption and SANS/USANS techniques. Energy & Fuels, 26(8), pp.5109–5120.
    [Google Scholar]
14. Melnichenko, Y.B., Wignall, G.D., Cole, D.R. and Frielinghaus, H.
    , 2006. Adsorption of supercritical CO 2 in aerogels as studied by small-angle neutron scattering and neutron transmission techniques. The Journal of chemical physics, 124(20), p. 204711.
    [Google Scholar]
15. Melnichenko, Y.B., Radlinski, A.P., Mastalerz, M., Cheng, G. and Rupp, J.
    , 2009. Characterization of the CO2 fluid adsorption in coal as a function of pressure using neutron scattering techniques (SANS and USANS). International Journal of Coal Geology, 77(1–2), pp.69–79.
    [Google Scholar]
16. Melnichenko, Y.B. and Wignall, G.D.
    , 2009. Density and volume fraction of supercritical CO2 in pores of native and oxidized aerogels. International Journal of Thermophysics, 30(5), p. 1578.
    [Google Scholar]
17. Melnichenko, Y.B., He, L., Sakurovs, R., Kholodenko, A.L., Blach, T., Mastalerz, M., Radliński, A.P., Cheng, G. and Mildner, D.F.
    , 2012. Accessibility of pores in coal to methane and carbon dioxide. Fuel, 91(1), pp.200–208.
    [Google Scholar]
18. Radliński, A.P., Boreham, C.J., Lindner, P., Randl, O., Wignall, G.D., Hinde, A. and Hope, J.M.
    , 2000. Small angle neutron scattering signature of oil generation in artificially and naturally matured hydrocarbon source rocks. Organic Geochemistry, 31(1), pp.1–14.
    [Google Scholar]
19. Rother, G., Melnichenko, Y.B., Cole, D.R., Frielinghaus, H. and Wignall, G.D.
    , 2007. Microstructural characterization of adsorption and depletion regimes of supercritical fluids in nanopores. The Journal of Physical Chemistry C, 111(43), pp.15736–15742.
    [Google Scholar]
20. Rother, G., Krukowski, E.G., Wallacher, D., Grimm, N., Bodnar, R.J. and Cole, D.R.
    , 2011. Pore size effects on the sorption of supercritical CO2 in mesoporous CPG-10 silica. The Journal of Physical Chemistry C, 116(1), pp.917–922.
    [Google Scholar]
21. Ruppert, L.F., Sakurovs, R., Blach, T.P., He, L., Melnichenko, Y.B., Mildner, D.F. and Alcantar-Lopez, L.
    , 2013. A USANS/SANS study of the accessibility of pores in the Barnett Shale to methane and water. Energy & Fuels, 27(2), pp.772–779.
    [Google Scholar]
22. Sakurovs, R., Koval, L., Grigore, M., Sokolova, A., Ruppert, L.F. and Melnichenko, Y.B.
    , 2018. Nanometre-sized pores in coal: Variations between coal basins and coal origin. International Journal of Coal Geology, 186, pp.126–134.
    [Google Scholar]
23. Wu, W.L.
    , 1982. Small-angle X-Ray study of particulate reinforced composites. Polymer, 23(13), pp.1907–1912.
    [Google Scholar]